It is known that a five-dimensional free vector field $A_M$ cannot be localized on Randall-Sundrum (RS)-like thick branes—namely, the thick branes embedded in asymptotic anti–de Sitter spacetime. To localize a vector field on the RS-like thick brane, an extra coupling term should be introduced. We generalize the geometrical coupling mechanism by adding two mass terms ($\alpha R{g}^{MN}{A}_M{A}_N+\beta R^{MN}{A}_M{A}_N$) to the action. We decompose the fundamental vector field $A_M$ into three parts: transverse vector part ${\hat{A}}_{\mu }$ and scalar parts $\varphi$ and $A_5$. Then we find that the transverse vector part ${\hat{A}}_{\mu }$ decouples from the scalar parts. To eliminate the tachyonic modes of ${\hat{A}}_{\mu }$, the two coupling parameters $\alpha$ and $\beta$ should satisfy a relation. Combining the restricted condition, we can get a combination parameter as $\gamma =\frac{3}{2}\pm \sqrt{1+12\alpha }$. Only if $\gamma >1/2$ can the zero mode of ${\hat{A}}_{\mu }$ be localized on the RS-like thick brane. We also investigate the resonant character of the vector part ${\hat{A}}_{\mu }$ for a general RS-like thick brane with a warp factor $A\left(z\right)=-\ln (1+k^2{z}^2)/2$ by choosing the relative probability method. The results show that the massive resonant Kaluza-Klein modes can exist only for $\gamma >3$. The number of resonant Kaluza-Klein states increases with the combination parameter $\gamma$, and the lifetime of the first resonant state can be as long as our Universe’s. This indicates that the vector resonances might be considered one of the candidates of dark matter. Combining the conditions of experimental observations, the constraint shows that the parameter $k$ has a lower limit with $k\gtrsim {10}^{-17}\mathrm{eV}$, the combination parameter $\gamma$ should be greater than 57, and, accordingly, the mass of the first resonant state should satisfy $m_1\gtrsim {10}^{-15}\mathrm{eV}$.