The qq-characters are powerful tools to reveal symmetries and integrabilities of Seiberg-Witten theories. The goal of this paper is to provide analytic expressions of qq-characters based on Young diagrams in 5d 𝒩 = 1 pure Yang-Mills theories with BCD-type gauge groups, by focusing on the unrefined limit. Using these expressions, we investigate the relationships among qq-characters of classical gauge groups. For SO(n) gauge groups, we construct a quantum-toroidal-like algebra via the Ward-identity approach, which allows us to derive the qq-characters.
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